The mass spectrum of an organic compound, Z, was recorded. The molecular ion peak is observed at m/z 84. The relative abundances of selected peaks are shown in the table.
| m/z | relative abundance / % |
|---|---|
| 84 | 100 |
| 85 | 5.5 |
| 86 | 32 |
| 29 | - |
There is also a fragment peak at m/z 29.
Explain how the mass spectrum of Z provides evidence for each of the following.
(i) The molecular mass of Z is 84. (ii) Z contains 5 carbon atoms. (iii) Z contains a chlorine atom. (iv) The fragment at m/z 29 is likely to be .