CAIE A Level Chemistry 9701 · Carboxylic acids and derivatives

Carboxylic acids and derivatives: explain question

Explain6 marksChallenge

The pH of a 0.1 mol dm−3^{-3} aqueous solution of chloroethanoic acid, ClCHX2COOH\ce{ClCH2COOH}, is lower than the pH of a 0.1 mol dm−3^{-3} aqueous solution of ethanoic acid, CHX3COOH\ce{CH3COOH}. Explain this observation in terms of the inductive effect and the stability of the conjugate base.

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