CAIE A Level Chemistry 9701 · Chemistry of transition elements

Chemistry of transition elements: explain question

Explain4 marksStandard

Aqueous cobalt(II) ions exist as the pink complex [Co(HX2O)X6]X2+\ce{[Co(H2O)6]^{2+}}. When concentrated hydrochloric acid is added, the solution turns blue as the complex [CoClX4]X2−\ce{[CoCl4]^{2-}} forms. Explain this colour change in terms of d-orbital splitting and the effect of ligands.

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