CAIE A Level Chemistry 9701 · Electrochemistry

Electrochemistry: explain question

Explain4 marksStandard

Two electrolytic experiments are described.

Experiment 1: An aqueous solution of sodium chloride is electrolysed using inert platinum electrodes. A very dilute solution is used, and then the experiment is repeated using a concentrated solution.

Experiment 2: A constant current is passed through an aqueous solution of copper(II) sulfate between a copper anode and a copper cathode. The mass loss of the anode is measured after a known time.

(a) Explain why the products at the electrodes differ between the dilute and concentrated solutions of sodium chloride.

(b) Explain how the data from Experiment 2 can be used to determine a value for the Avogadro constant. Include in your answer the relationship between the Faraday constant, FF, the Avogadro constant, LL, and the charge on the electron, ee.

0 words · 4 marks

No account needed for your first marks. Your answer is used only to mark it.

How this question is marked

4 marks, so the mark scheme is looking for about 4 separate creditworthy points. Making the same point twice in different words earns it once.

Explain means: Give the reasons or the mechanism: why or how something happens. Link each point to the next with because, so or which means. A list of facts with no links usually loses the reasoning marks.

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