CAIE A Level Chemistry 9701 · Electrochemistry

Electrochemistry: explain question

Explain4 marksStandard

A student wants to measure the standard electrode potential of the FeX3+/FeX2+\ce{Fe^{3+}/Fe^{2+}} half-cell. The student sets up a cell with a platinum electrode dipped into a solution containing both FeX3+(aq)\ce{Fe^{3+}(aq)} and FeX2+(aq)\ce{Fe^{2+}(aq)} ions, each at a concentration of 1 mol dm−3^{-3}, and connects this half-cell to a standard hydrogen electrode. The student records a cell potential of +0.77 V.

Explain why a platinum electrode is used in the FeX3+/FeX2+\ce{Fe^{3+}/Fe^{2+}} half-cell, what the +0.77 V reading represents, and how the student knows the polarity of the platinum electrode in this cell.

0 words · 4 marks

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4 marks, so the mark scheme is looking for about 4 separate creditworthy points. Making the same point twice in different words earns it once.

Explain means: Give the reasons or the mechanism: why or how something happens. Link each point to the next with because, so or which means. A list of facts with no links usually loses the reasoning marks.

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