A plant extract is separated by chromatography on a plate coated with aluminium oxide. The solvent is a non-polar hydrocarbon. Two pigments are separated: pigment A has Rf = 0.85 and pigment B has Rf = 0.30. Explain, in terms of the stationary phase and the mobile phase, why pigment A has a higher Rf value than pigment B.
CAIE A Level Chemistry 9701 · Analytical techniques
Analytical techniques: explain question
Explain5 marksChallenge
How this question is marked
5 marks, so the mark scheme is looking for about 5 separate creditworthy points. Making the same point twice in different words earns it once.
Explain means: Give the reasons or the mechanism: why or how something happens. Link each point to the next with because, so or which means. A list of facts with no links usually loses the reasoning marks.
More Analytical techniques questions
- 7 marks · In an experiment using thin-layer chromatography, a mixture of three compounds A, B and C is separated. The stationary phase is aluminium…
- 5 marks · A student records an infrared spectrum of a colourless liquid with molecular formula C3H5N. The spectrum shows a sharp, strong absorption…
- 6 marks · A reaction mixture is analysed by gas–liquid chromatography using a non-polar stationary phase and nitrogen as the mobile phase. The…
- 5 marks · The carbon-13 NMR spectrum of benzene, C6H6, shows only one peak, at about 128 ppm. Explain why the spectrum of benzene shows only one peak.
- 7 marks · A compound has the molecular formula C4H8. Its carbon-13 NMR spectrum shows exactly two peaks. Compare the possible structures of this…
- 5 marks · A mixture of three liquid organic compounds is separated by gas-liquid chromatography. The chromatograph uses a non-polar stationary phase…
Written by Markquill to follow the Cambridge International syllabus. Markquill is independent and is not affiliated with or endorsed by Cambridge International.