CAIE A Level Chemistry 9701 · Analytical techniques

Analytical techniques: describe question

Describe6 marksChallenge

A reaction mixture is analysed by gas–liquid chromatography using a non-polar stationary phase and nitrogen as the mobile phase. The chromatogram shows two peaks, P and Q. Peak P appears at a retention time of 2.5 minutes and peak Q at 8.0 minutes. The areas under the peaks are proportional to the amount of each substance present. The mixture is known to contain two compounds, X and Y, of similar molar mass. Compound X is non-polar; compound Y is polar.

Describe how this chromatogram allows the mixture to be separated and analysed. In your answer, refer to the stationary phase, the mobile phase, the retention times of P and Q, and the information that can be obtained about the composition of the mixture.

0 words · 6 marks

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6 marks, so the mark scheme is looking for about 6 separate creditworthy points. Making the same point twice in different words earns it once.

Describe means: Say what happens or what something is like, in order and with detail. You are not being asked why. If there is data, quote it: name the trend, then give figures with units at the points where it changes.

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