CAIE A Level Chemistry 9701 · Chemistry of transition elements

Chemistry of transition elements: compare question

Compare5 marksStandard

Two nickel(II) complexes are studied. Complex A is [Ni(HX2NCHX2CHX2NHX2)X2(HX2O)X2]X2+\ce{[Ni(H2NCH2CH2NH2)2(H2O)2]^2+} and complex B is [Ni(HX2NCHX2CHX2NHX2)X3]X2+\ce{[Ni(H2NCH2CH2NH2)3]^2+}.

Compare the types of stereoisomerism shown by these complexes. In your answer, refer to the conditions required for each type of isomerism and the overall polarity of any isomers formed.

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