A voltaic cell is constructed by connecting a Pb(s)∣PbX2+(aq) half-cell to an Ag(s)∣AgX+(aq) half-cell. The standard electrode potentials are:
PbX2+(aq)+2eX−Pb(s)E∘=−0.13 VAgX+(aq)+eX−Ag(s)E∘=+0.80 V
Explain the polarity of the electrodes, the direction of electron flow in the external circuit, and identify the species that is oxidised and reduced. Construct the overall redox equation for the cell reaction.
How this question is marked
4 marks, so the mark scheme is looking for about 4 separate creditworthy points. Making the same point twice in different words earns it once.
Explain means: Give the reasons or the mechanism: why or how something happens. Link each point to the next with because, so or which means. A list of facts with no links usually loses the reasoning marks.
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