CAIE A Level Chemistry 9701 · Analytical techniques

Analytical techniques: describe question

Describe7 marksChallenge

The following data were obtained from a gas-liquid chromatographic analysis of a mixture of three alkanes: pentane, hexane and heptane.

AlkaneRetention time / minPeak area / arbitrary units
pentane2.545
hexane4.860
heptane8.230

(a) Describe the stationary phase and the mobile phase used in gas-liquid chromatography. (b) Explain the meaning of the term 'retention time' and account for the order of retention times of the three alkanes in terms of their interactions with the stationary phase. (c) Describe how the percentage composition of the mixture can be determined from the data in the table, and state which alkane is present in the highest percentage.

0 words · 7 marks

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7 marks, so the mark scheme is looking for about 7 separate creditworthy points. Making the same point twice in different words earns it once.

Describe means: Say what happens or what something is like, in order and with detail. You are not being asked why. If there is data, quote it: name the trend, then give figures with units at the points where it changes.

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