CAIE A Level Chemistry 9701 · Analytical techniques

Analytical techniques: compare question

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A chemist uses X1X221H\ce{^1H} NMR spectroscopy to analyse two organic compounds, ethanol (CHX3CHX2OH\ce{CH3CH2OH}) and methoxymethane (CHX3OCHX3\ce{CH3OCH3}). Compare the X1X221H\ce{^1H} NMR spectra of these two compounds. In your answer you should discuss the number of signals, chemical shifts, splitting patterns, relative peak areas, the use of DX2O\ce{D2O}, and the role of tetramethylsilane (TMS) and deuterated solvents in the NMR experiment.

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5 marks, so the mark scheme is looking for about 5 separate creditworthy points. Making the same point twice in different words earns it once.

Compare means: Give similarities or differences between two things, and say which side each point belongs to. Write each point as a pair, for example: A is X, whereas B is Y. Two separate descriptions rarely earn the marks.

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