CAIE A Level Chemistry 9701 · Chemical energetics

Chemical energetics: compare question

Compare5 marksStandard

Reaction 1: ΔH = +100 kJ mol⁻¹, ΔS = +200 J K⁻¹ mol⁻¹ Reaction 2: ΔH = −100 kJ mol⁻¹, ΔS = −200 J K⁻¹ mol⁻¹

Compare the feasibility of these two reactions at different temperatures. In your answer, use the Gibbs equation ΔG = ΔH − TΔS and explain how the sign of ΔG determines feasibility. Describe how changing temperature affects the feasibility of each reaction, referring to the magnitude and sign of the terms.

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How this question is marked

5 marks, so the mark scheme is looking for about 5 separate creditworthy points. Making the same point twice in different words earns it once.

Compare means: Give similarities or differences between two things, and say which side each point belongs to. Write each point as a pair, for example: A is X, whereas B is Y. Two separate descriptions rarely earn the marks.

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