CAIE A Level Chemistry 9701 · Chemistry of transition elements

Chemistry of transition elements: describe question

Describe5 marksStandard

An octahedral cobalt(III) complex has the formula [Co(NHX3)X4ClX2]X+\ce{[Co(NH3)4Cl2]+}. The two chloride ligands can be arranged either on adjacent positions or on opposite positions. (a) Name the type of stereoisomerism shown by this complex. (b) State whether this complex is polar or non-polar in each of the two arrangements, and explain your reasoning. (c) State, with a reason, whether the complex [Co(NHX3)X4ClX2]X+\ce{[Co(NH3)4Cl2]+} shows optical isomerism.

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