Two experiments are set up for the reaction between aqueous and aqueous . In experiment 1, the concentration of is doubled while the volume and the concentration of are kept the same. In experiment 2, the pressure of a gaseous reaction is doubled by compressing the mixture to half its volume at constant temperature.
Compare the effect of doubling the concentration of in experiment 1 with the effect of doubling the pressure in experiment 2, in terms of the frequency of effective collisions.