CAIE A Level Chemistry 9701 · Equilibria

Equilibria: suggest question

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Agricultural soil is often treated with lime (CaCOX3\ce{CaCO3}) to raise its pH. The carbonate–hydrogencarbonate buffer system in the soil is represented by:

COX3X2−(aq)+HX2O(l)⇌HCOX3X−(aq)+OHX−(aq)\ce{CO3^{2-}(aq) + H2O(l) <=> HCO3^{-}(aq) + OH^{-}(aq)}

A soil scientist adds a small amount of a strong acid, such as HCl\ce{HCl}, to a sample of this soil. Suggest how the buffer system minimises the change in pH. In your answer, refer to the equilibrium above and to the conjugate acid–base pair involved.

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